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I’m not an knowledgeable, but it surely looks like Freedom is routing an iPhone’s community visitors via a “native” VPN. Which means, when you might open an app like Chrome and navigate to google.com, Freedom’s VPN wouldn’t ahead the request.
I have never put in or examined the app, however their web site is fastidiously worded: “Set up App Blocker” to put in the Freedom app blocker. This blocks content material on different browsers like Google Chrome and for apps.”
I learn “blocks content material” to imply you may open the app, however it would fail to load content material and not using a community connection. I have never examined, however I think that you possibly can nonetheless use “offline” apps.
Here’s a display seize of their web site.

As you famous, Apple’s cell gadget administration (MDM) resolution is able to stopping apps and different actions. Right here is the listing for MDM restrictions, and a listing of Supervised restrictions.
It is my perception {that a} third-party app can not forestall one other app from functioning. Freedom is enjoying a community trick. To cease an app from really booting would require a jailbreak. However I have never explored this area in depth.
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